MITE0000355
MITE0000356
MITE0000357
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Reaction Information

Number of Known Reactions: 2

Reaction 1
reaction SMARTS
Description Dehydrogenation of meroterpenoid precursor before cyclization in the anditomin biosynthetic pathway.
Tailoring
  • Dehydrogenation
Database References
Evidence
  • Heterologous expression
  • In vitro assay
References
Example 1
Metadata
  • Description: Conversion of preandiloid B yielding the enone preandiloid C.
  • Intermediate: True
Substrate 1 substrate SMILES
Product 1 product SMILES
Reaction 2
reaction SMARTS
Description Structural rearrangement generating a bicyclo[2.2.2]octane core in the anditomin biosynthetic pathway.
Tailoring
  • Cyclization
Database References No database crosslinks available
Evidence
  • Heterologous expression
  • In vitro assay
References
Example 1
Metadata
  • Description: Conversion of preandiloid C to andiconin.
  • Intermediate: True
Substrate 1 substrate SMILES
Product 1 product SMILES

Enzyme Information

Accession IDMITE0000356
Entry StatusStatus: active
Enzyme NameAndA
Enzyme DescriptionDioxygenase
Database References
Cofactors
  • Organic
    • Ascorbic acid
    • a-Ketoglutaric acid
  • Inorganic
    • Fe
References
CommentNonheme iron-dependent dioxygenase
Enzyme Visualization (AlphaFold-predicted)

Version 1 (2026-05-16)

Contributor(s)
Reviewer(s)
Comment "New entry. Reviewer 1 improved descriptions."