{
    "accession": "MITE0000226",
    "status": "active",
    "changelog": [
        {
            "version": "1",
            "date": "2025-11-11",
            "contributors": [
                "0000-0002-8834-593X"
            ],
            "reviewers": [
                "0000-0002-8323-5416"
            ],
            "comment": "New entry."
        }
    ],
    "enzyme": {
        "name": "StmC",
        "description": "Glycosyltransferase",
        "references": [
            "doi:10.1021/jacs.3c12895"
        ],
        "databaseIds": {
            "uniprot": "UPI0005831253",
            "genpept": "KIA76014.1"
        }
    },
    "reactions": [
        {
            "tailoring": [
                "Glycosylation"
            ],
            "description": "Glycosylation of stromemycin in Aspergillus ustus",
            "reactionSMARTS": "[#6:1]1:[#6:5](-[#8:17]):[#6:6]:[#6:4](-[#6:22]-[#6:23]-[#6:24]=[#6:25]-[#6:26]=[#6:27]-[#6:28]-[#6:29]-[#6:30]):[#6:2](-[#6:7](=[#8:9])-[#8:8]-[#6:10]2:[#6:14]:[#6:15](-[#6:31]-[#6:32]-[#6:33]=[#6:34]-[#6:35]=[#6:36]-[#6:37]-[#6:38]-[#6:39]):[#6:13](-[#6:19](=[#8:21])-[#8:20]):[#6:11](-[#8:18]):[#6:12]:2):[#6:3]:1-[#8:16]>>[#6:1]1(-[#6]2-[#8]-[#6](-[#6]-[#8])-[#6](-[#8])-[#6](-[#8])-[#6]-2-[#8]):[#6:5](-[#8:17]):[#6:6]:[#6:4](-[#6:22]-[#6:23]-[#6:24]=[#6:25]-[#6:26]=[#6:27]-[#6:28]-[#6:29]-[#6:30]):[#6:2](-[#6:7](=[#8:9])-[#8:8]-[#6:10]2:[#6:14]:[#6:15](-[#6:31]-[#6:32]-[#6:33]=[#6:34]-[#6:35]=[#6:36]-[#6:37]-[#6:38]-[#6:39]):[#6:13](-[#6:19](=[#8:21])-[#8:20]):[#6:11](-[#8:18]):[#6:12]:2):[#6:3]:1-[#8:16]",
            "reactions": [
                {
                    "substrate": "CCCC=CC=CCCc1cc(OC(=O)c2c(O)cc(O)cc2CCC=CC=CCCC)cc(O)c1C(=O)O",
                    "products": [
                        "CCCC=CC=CCCc1cc(OC(=O)c2c(CCC=CC=CCCC)cc(O)c(C3OC(CO)C(O)C(O)C3O)c2O)cc(O)c1C(=O)O"
                    ],
                    "isIntermediate": true
                }
            ],
            "evidence": {
                "evidenceCode": [
                    "Heterologous expression",
                    "In vitro assay"
                ],
                "references": [
                    "doi:10.1021/jacs.3c12895"
                ]
            }
        }
    ]
}