{
    "accession": "MITE0000165",
    "status": "active",
    "comment": "Previously referenced retired MIBiG ID BGC0003093.",
    "changelog": [
        {
            "version": "1",
            "date": "2024-07-30",
            "contributors": [
                "AAAAAAAAAAAAAAAAAAAAAAAA"
            ],
            "reviewers": [
                "0000-0003-0443-9902"
            ],
            "comment": "Initial entry. Reviewer fixed reactionSMARTS:reactionSMARTS."
        },
        {
            "version": "2",
            "date": "2026-07-03",
            "contributors": [
                "AAAAAAAAAAAAAAAAAAAAAAAA"
            ],
            "reviewers": [
                "0000-0001-6534-6609"
            ],
            "comment": "Removed retired MIBIG ID."
        }
    ],
    "enzyme": {
        "name": "PhoN",
        "description": "Isomerase",
        "references": [
            "doi:10.1021/acs.orglett.2c01050"
        ],
        "databaseIds": {
            "genpept": "UPG58743.1"
        }
    },
    "reactions": [
        {
            "tailoring": [
                "Other"
            ],
            "reactionSMARTS": "[#6:4]-[#6:3]-1=[#6:5]-[#6:6](=[O:7])-[#6:8](-[#6:9](=[O:10])-[c:11]2[c:12](-[#8:13])[c:14][c:15][c:16][c:17]2-[#8:18])=[#6:19](-[#6:20]-[#8:21])-[#6@@H:1]-1-[#8:2]>>[#6:1]-[#6@@H:2]-1-[#6:3]-[#6:4](=[O:5])-[#6:6](-[#6:7](=[O:8])-[c:9]2[c:10](-[#8:11])[c:12][c:13][c:14][c:15]2-[#8:16])=[#6:17](-[#6:18]-[#8:19])-[#6:20]-1=[O:21]",
            "reactions": [
                {
                    "substrate": "CC1=CC(=O)C(C(=O)c2c(O)cccc2O)=C(CO)[C@@H]1O",
                    "products": [
                        "C[C@@H]1CC(=O)C(C(=O)c2c(O)cccc2O)=C(CO)C1=O"
                    ],
                    "isIntermediate": true
                }
            ],
            "evidence": {
                "evidenceCode": [
                    "Heterologous expression"
                ],
                "references": [
                    "doi:10.1021/acs.orglett.2c01050"
                ]
            }
        }
    ]
}