{
    "accession": "MITE0000147",
    "status": "active",
    "changelog": [
        {
            "version": "1",
            "date": "2024-07-30",
            "contributors": [
                "0009-0003-1714-1678"
            ],
            "reviewers": [
                "0000-0003-0443-9902"
            ],
            "comment": "Initial entry. Reviewer fixed general aromaticity."
        }
    ],
    "enzyme": {
        "name": "PeuJ",
        "description": "FMN-dependent monooxygenase",
        "references": [
            "doi:10.1007/s00253-023-12385-8"
        ],
        "databaseIds": {
            "genpept": "ATW47938.1",
            "mibig": "BGC0002964"
        }
    },
    "reactions": [
        {
            "tailoring": [
                "Hydroxylation"
            ],
            "reactionSMARTS": "[#6:1]-[#6:2]\\[#6:3]=[#6:4]\\[c:5]1[c:6]-2[o:7][c:8](-[#6:9]-[#6:10](=[O:11])-[#8:12]-[#6:13]/[#6:14](=[#6:15]\\[#6:16](\\[#6:17]-[#6:18])=[#6:19]\\[#6:20]-[#6:21])/[#6:22]=[#6:23]/[#6:24](-[#8:25])-[#6:26]-2-[#8:27])[c:28][c:29]1=[O:30]>>[#6:1]-[#6:2]\\[#6:3]=[#6:4](/[#6:5]-[#6:6])\\[#6:7]=[#6:8]-1/[#6:9]-[#8:10]-[#6:11](=[O:12])-[#6:13]-[c:14]2[c:15][c:16](=[O:17])[c:18](\\[#6:19]=[#6:20]\\[#6:21](-[#6:22])-[#8:23])[c:24]([o:25]2)-[#6:26](-[#8:27])-[#6:28](-[#8:29])/[#6:30]=[#6:31]/1",
            "reactions": [
                {
                    "substrate": "CC/C=C/c1c2oc(cc1=O)CC(=O)OCC(=C\\C(=C\\CC)CC)/C=C/C(O)C2O",
                    "products": [
                        "CC/C=C(/C=C1/C=C/C(O)C(O)c2oc(cc(=O)c2/C=C/C(C)O)CC(=O)OC1)CC"
                    ],
                    "isIntermediate": false
                }
            ],
            "evidence": {
                "evidenceCode": [
                    "Knock-out studies"
                ],
                "references": [
                    "doi:10.1007/s00253-023-12385-8"
                ]
            }
        }
    ]
}